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Record W2115788728 · doi:10.1002/anie.200806208

Simple Synthesis of Graphitic Ordered Mesoporous Carbon Materials by a Solid‐State Method Using Metal Phthalocyanines

2009· article· en· W2115788728 on OpenAlexaff
Kyu Tae Lee, Xiulei Ji, Mathieu Rault, Linda F. Nazar

Bibliographic record

VenueAngewandte Chemie International Edition · 2009
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsMesoporous materialMaterials scienceCarbon fibersMetalChemical vapor depositionNanotechnologyMesoporous silicaSolid-stateChemical engineeringCatalysisChemistryOrganic chemistryComposite materialMetallurgyComposite numberPhysical chemistry

Abstract

fetched live from OpenAlex

Law and order: When metal phthalocyanines are used as the carbon precursor, pseudo-solid-state in situ chemical vapor deposition on mesoporous silica yields highly graphitic mesoporous carbon materials (see TEM image) with ordered pore structure, high surface area, and high pore volume. This simple synthetic route is suitable for bulk production, and the high degree of graphitization is enhanced by the catalytic action of the metal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.937

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.289
Teacher spread0.271 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations132
Published2009
Admission routes1
Has abstractyes

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