Fourier transform Raman spectroscopic study of pressure‐induced ligand bond activation in a molybdenum–sulfur cluster
Bibliographic record
Abstract
Abstract Fourier transform Raman spectra of the prototype, triangular, transition metal–sulfur cluster anion [Mo 3 (S 2 ) 6 S] 2− were recorded at pressures up to 60 kbar with the aid of a diamond‐anvil cell (DAC). The pressure dependences (∂ν/∂ p ) of the Raman bands indicate a structural change at around 10–15 kbar. The SS stretching mode for the bridging disulfide ligands exhibits a slightly negative ∂ν/∂ p value (−0.08), suggesting that SS bonds are weakened, i.e. activated , at high pressures. This pressure‐induced activity parallels the observed nucleophilic substitution reactivity of the S 2 groups in this molybdenum cluster anion. In view of this, a preliminary investigation of the reaction between [Mo 3 (S 2 ) 6 S] 2− and CN − was undertaken in the solid state in the DAC under high pressure. Copyright © 2002 John Wiley & Sons, Ltd.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".