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Record W2117729045 · doi:10.1021/jp027724c

Three-Dimensional Structure of Electroosmotic Flow over Heterogeneous Surfaces

2003· article· en· W2117729045 on OpenAlexaff
David Erickson, Dongqing Li

Bibliographic record

VenueThe Journal of Physical Chemistry B · 2003
Typearticle
Languageen
FieldEngineering
TopicMicrofluidic and Capillary Electrophoresis Applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMicroscale chemistryElectrokinetic phenomenaMicrochannelFlow (mathematics)Streamlines, streaklines, and pathlinesMechanicsElectric fieldElectro-osmosisMicrofluidicsChemistryCharge densityChemical physicsMaterials scienceNanotechnologyPhysicsElectrophoresisChromatography

Abstract

fetched live from OpenAlex

Electroosmotic flow is widely used as a primary method of species transport in microscale biological and chemical analysis systems commonly referred to as labs-on-a-chip. In these systems, surface electrokinetic heterogeneity can be introduced either intentionally through micromanufacturing technology, such as microcontact printing, or unintentionally through, for example, bioparticle adhesion. In either case it is desirable to examine the influence of these surface heterogeneities on the electroosmotic flow structure. In this paper a numerical model based on a simultaneous solution to the Nernst−Planck, Poisson, and Navier−Stokes equations is used to examine the electroosmotically driven flow through a microchannel exhibiting a periodically repeating patchwise heterogeneous surface pattern. The simulations have revealed a distinct three-dimensional flow structure that, depending on the degree of heterogeneity, varies from a weak circulation perpendicular to the applied electric field to a fully circulatory flow system. In general the induced flow structure is found to penetrate into the bulk flow no deeper than the length scale of the heterogeneous patches. In addition the electrophoritic influence of the applied electric field on the net charge density in the double layer is shown to cause a significant deviation from the traditional Poisson−Boltzmann distribution. The overall effect of this double-layer rearrangement on the flow structure, however, is found to be negligible.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score0.298

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.189
Teacher spread0.185 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations45
Published2003
Admission routes1
Has abstractyes

Explore more

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