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Record W2119701532 · doi:10.1002/cjce.21752

New algebraic expressions for thermodiffusion in binary <i>n</i>‐alkane mixtures

2012· article· en· W2119701532 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
venuePublished in a venue whose home country is Canada.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2012
Typearticle
Languageen
FieldEngineering
TopicField-Flow Fractionation Techniques
Canadian institutionsToronto Metropolitan University
FundersCanadian Space AgencyEuropean Space Agency
KeywordsAlkaneThermodynamicsBinary numberAlgebraic numberSimple (philosophy)Statistical physicsViscosityMaterials scienceHydrocarbonMathematicsChemistryPhysicsOrganic chemistryMathematical analysis

Abstract

fetched live from OpenAlex

Abstract Following a detailed analysis of the experimental data on thermodiffusion coefficients of numerous binary hydrocarbon mixtures from over 90 experiments, four new algebraic expressions are proposed. As per these formulations, the thermodiffusion coefficient of binary n ‐alkane mixtures can be expressed as a function of the chemical composition of the mixture and the mixture properties such as density and viscosity. Detailed experimental validation is presented using four n ‐alkane series containing a wide range of combinations of n ‐alkanes. Additionally, comparison with recently proposed neural network model and a model based on the principles of non‐equilibrium thermodynamics is also presented. It has been found that the proposed algebraic models are simple in formulations, are evaluated with least computational effort and yet have a very high accuracy in predicting the thermodiffusion coefficients. © 2012 Canadian Society for Chemical Engineering

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.043
Threshold uncertainty score0.336

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.203
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it