Structural Study on the Complex of Ortho-Ester Tetra Azophenylcalix[4]arene (TEAC) with Th(IV)
Bibliographic record
Abstract
A new 1:1 complex between Ortho-Ester Tetra-Azophenylcalix[4]arene (TEAC) and Thorium(IV) was found in weakly acidic medium (pH =4-5), ?max = 520 nm, Beer’s law was obeyed in the range 2.5 ×10-6 – 2.5×10-5 mol.L-1 of Th(IV), the limit of detection was 1.0 × 10? 6 mol.L-1 and linear regression equation was determined to be: absorbance (A) = 0,248×C(10-5 mol.L-1) + 0,02 (R2 = 0,990, n =7). The FT-IR, HNMR, Raman spectroscopies were also used to provide the existence of this complex, and the Molecular Mechanics (MM) method in Arguslab software was applied to optimize the structure. The energy of the system, QEq charge, bond lengths and bond angles were also calculated by this program. Combining all data, the structure of complex TEAC - Th(IV) has been proposed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".