Alkylsilyl Compounds of Selenium and Tellurium: New Precursors for ALD
Why this work is in the frame
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Bibliographic record
Abstract
Several alkylsilyl compounds of selenium and tellurium were synthesized and characterized. Crystal structures of (tBuMe2Si)2Se and (tBuMe2Si)2Te were solved. Thermal properties of the compounds were studied with TGA. It was found that these compounds are very volatile and thermally stable therefore suitable ALD precursors. Reactivity of the compounds was preliminarily studied by mixing the compounds with different metal precursors in solution. It was found that the compounds are highly reactive against many metal halides and other metal compounds. They have also been tested successfully in ALD. For Ge2Sb2Te5 low growth temperature (60-90 oC) was found the most suitable while ZnSe and ZnTe films were grown at 400 {degree sign}C.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it