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Record W2122441559 · doi:10.1039/c2an36296a

Theoretical estimation of drag tag lengths for direct quantitative analysis of multiple miRNAs (DQAMmiR)

2012· article· en· W2122441559 on OpenAlexaff
Leonid T. Cherney, Sergey N. Krylov

Bibliographic record

VenueThe Analyst · 2012
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicAdvanced biosensing and bioanalysis techniques
Canadian institutionsYork University
Fundersnot available
KeywordsDragOligonucleotidemicroRNADNAComputational biologyBiological systemElectrophoresisChemistryRNACapillary electrophoresisDrag coefficientChromatographyBiologyGeneBiochemistryPhysicsMechanics

Abstract

fetched live from OpenAlex

To better understand the regulatory roles of miRNA in biological functions and to use miRNA as molecular markers of diseases, we need to accurately measure amounts of multiple miRNAs in biological samples. Direct quantitative analysis of multiple miRNAs (DQAMmiR) has been recently developed by using a classical hybridization approach where miRNAs are hybridized with fluorescently labeled complementary DNA probes taken in excess, and the amounts of the hybrids and the unreacted probes are measured to calculate the amount of miRNAs. Capillary electrophoresis was used as an instrumental platform for analysis. The problem of separating the unreacted probes from the hybrids was solved by adding SSB to the run buffer. A more difficult problem of separating hybrids from each other was solved by attaching different drag tags to the probes. Biotin and a hairpin-forming extension on the probe were used as two drag tags in the proof-of-principle work. Making DQAMmiR a generic approach requires a generic solution for drag tags. Peptides have been suggested as drag tags for long oligonucleotides in DNA sequencing by electrophoresis. Here we theoretically consider short peptides of different lengths as drag tags for DQAMmiR. We find analytical equations that allow us to estimate mobilities of RNA-DNA hybrids with peptide drag tags of different lengths. Our calculations suggest that the mobility shifts required for DQAMmiR can be achieved with the length of peptide chains in the ranges of 5-20 residues for five miRNAs and 2-47 residues for nine miRNAs. Peptides of these lengths can be feasibly synthesized with good yield and purity. The results of this theoretical study will guide the design and production of hybridization probes for DQAMmiR.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.082
Threshold uncertainty score0.310

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.321
Teacher spread0.306 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2012
Admission routes1
Has abstractyes

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