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Record W2123409092 · doi:10.1002/pssc.201084112

Photoinduced dichroism and the lack of a field effect

2011· article· en· W2123409092 on OpenAlexafffund
Robert E. Johanson, Matthew Kowalyshyn, Safa Kasap

Bibliographic record

VenuePhysica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics · 2011
Typearticle
Languageen
FieldMaterials Science
TopicPhase-change materials and chalcogenides
Canadian institutionsUniversity of Saskatchewan
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsDichroismCircular dichroismChemistryElectric fieldChalcogenidePolarization (electrochemistry)Linear dichroismElectronPhotochemistryMolecular physicsChemical physicsCrystallographyOpticsPhysicsPhysical chemistry

Abstract

fetched live from OpenAlex

Abstract The phenomenon of photoinduced dichroism in chalcogenide glasses requires a structural rearrangement of atoms in the localized region where the photon is absorbed. The structural change is facilitated by the energy released during electron‐hole recombination. The dichroism is induced because regions that preferentially absorb the incident polarization will be those that suffer the atomic rearrangements thus bleaching the material for that polarization. A strong electric field should break geminate pairs and transport the electron and hole away from the absorbing region which should quench the photoinduced dichroism. We have searched for such a field effect in glassy arsenic selenide at fields up to 10 V/μm. No decrease in the rate of induced dichroism is observed (the rate actually increases by about 10%) and no change is observed in the stretching parameter when the time dependence is fit to a stretched exponential. These results are consistent with those of other researchers who also failed to find a field effect. The implications of these results for the theory of photoinduced dichroism are discussed. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.124
GPT teacher head0.384
Teacher spread0.260 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2011
Admission routes2
Has abstractyes

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Same venuePhysica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physicsSame topicPhase-change materials and chalcogenidesFrench-language works237,207