Bibliographic record
Abstract
The synthesis of three octapyrrolic, 810, and four dodecapyrrolic, 1518, oligomers is reported. They are linear poly(dipyrromethene)s and potential ligands as building blocks for supramolecular architectures through self-assembly. Octapyrrolic oligomers 810 were prepared in 9095% yields by condensation of 2 equiv of a tripyrrolic compound 4 with 1 equiv of diformyldipyrrolic compounds 57. A similar procedure, involving the condensation of 2 equiv of a pentapyrrolic starting material 13 with 1 equiv of 57 or 14, was found to give rise to the corresponding dodecameric systems 1518 in 4156% yields.Key words: poly(dipyrromethene), linear polypyrroles, dipyrromethane, dipyrromethene.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".