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Record W2125195942 · doi:10.1142/s1793292014500908

HIGHLY CATALYTIC<font>Ag</font>/<font>Co</font><sub>3</sub><font>O</font><sub>4</sub>NANOCATALYSTS FABRICATED FOR<font>RhB</font>DYE DEGRADATION THROUGH A SIMPLE SILVER-MIRROR REACTION UNDER VISIBLE LIGHT

2014· article· en· W2125195942 on OpenAlexaff
Xiaolei Si, Guangliang Chen, Zhili Chen, Jun Huang, Shihua Chen, Sylvain Massey

Bibliographic record

VenueNANO · 2014
Typearticle
Languageen
FieldChemistry
TopicNanomaterials for catalytic reactions
Canadian institutionsUniversité de Sherbrooke
FundersNational Natural Science Foundation of China
KeywordsX-ray photoelectron spectroscopyRhodamine BMaterials scienceNanomaterial-based catalystCatalysisTransmission electron microscopyScanning electron microscopeAnalytical Chemistry (journal)NanoparticleChemical engineeringPhotochemistryNanotechnologyChemistryPhotocatalysisOrganic chemistry

Abstract

fetched live from OpenAlex

In this paper, a highly catalytic and nanosized Ag / Co 3 O 4 composite for rhodamine B ( RhB ) degradation was fabricated by using the co-precipitation method at room temperature. The Ag / Co 3 O 4 structure and catalytic properties were characterized through scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) gas-sorption measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-Vis spectroscopy. The results showed that the Co 3 O 4 nanosheets prepared by hydrothermal synthesis mainly exposed (2 2 0) and (1 1 1) facets, which played an important role in determining its catalytic oxidation performance. The Co 3 O 4 nanosheets doped with Ag nanoparticles by a simple silver-mirror reaction exhibited a stable and well-dispersed property in dye solution. Compared to the Ag and Co 3 O 4 nanostructure, the Ag nanoparticles with bigger diameter (10 nm) on Co 3 O 4 surface also readily produced surface-active oxygen species and exhibited a higher catalytic activity for the degradation of RhB solution (5 mg ⋅ L -1 ) under the visible light. The kinetic constant K of Ag / Co 3 O 4 catalyst for RhB degradation reaction was evaluated to 0.02724 min -1 , which is relatively higher than those reported in the literatures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.089
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0030.004
Meta-epidemiology (broad)0.0040.002
Bibliometrics0.0010.002
Science and technology studies0.0020.001
Scholarly communication0.0010.004
Open science0.0030.001
Research integrity0.0030.002
Insufficient payload (model declined to judge)0.0000.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.259
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2014
Admission routes1
Has abstractyes

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