<sup>129</sup>Xe and <sup>2</sup>H nuclear magnetic resonance (NMR) of xenon and deuterated-chloroform solutes in a thermotropic biaxial nematic liquid crystal
Bibliographic record
Abstract
Properties of a thermotropic nematic liquid crystal (LC) TM35 (organosiloxane tetrapode) were investigated by means of nuclear magnetic resonance (NMR) spectroscopy of probe atoms and molecules. 129Xe isotope enriched xenon gas and 2H isotope enriched chloroform were used as probes. Both 129Xe and 2H NMR measurements were carried out over a wide temperature range, covering isotropic, nematic, and glass phases. A clear change in the behavior of the LC is observed within the nematic phase at 289 K by changing the temperature from low to high and inspecting the spectral line width. The derivative curve of the 129Xe chemical shift also reveals a change at 289 K. These changes may be an indication of hindered molecular rotation around the long axis, and the appearance of a biaxial nematic phase.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".