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Record W2125587597 · doi:10.1002/ejic.201100038

A Rare μ<sub>4</sub>‐O Centred Dy<sub>4</sub> Tetrahedron with Coordination‐Induced Local Chirality and Single‐Molecule Magnet Behaviour

2011· article· en· W2125587597 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEuropean Journal of Inorganic Chemistry · 2011
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsCanadian Network for Innovation in EducationUniversity of Ottawa
FundersUniversity of Ottawa
KeywordsChemistrySingle-molecule magnetIntramolecular forceChirality (physics)TetrahedronAntiferromagnetismCrystallographyMagnetMoleculeLigand (biochemistry)LanthanideDiazineStereochemistryCondensed matter physicsMagnetizationPhysicsMagnetic field

Abstract

fetched live from OpenAlex

Abstract Coordination‐induced chirality was achieved in a uniquetetrahedral [Dy 4 (μ 4 ‐O)(μ‐OMe) 2 (beh) 2 (esh) 4 ] · 3MeOH complex through a twisted diazine bridge from a Schiff base ligand. Magnetic measurements reveal weak intramolecular antiferromagnetic interactions ( J = –0.3 cm –1 ) with single‐molecule magnet behaviour ( U eff = 23.42 K).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.022
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.196
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it