Morphology Development in Novel Composition of Thermoplastic Vulcanizates Based on PA12/PDMS Reactive Blends
Why this work is in the frame
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Bibliographic record
Abstract
Abstract The main objective of the present work was to tailor a new thermoplastic vulcanisate (TPV) composed of PA 12 as the thermoplastic phase and PDMS as the rubber phase. The PDMS was crosslinked by dicumyl peroxide (DCP). Interestingly, addition of 2,2,6,6‐tetramethylpiperidinyloxyl (TEMPO) to the TPV provided the compatibilization of the PA12/PDMS blend in the dynamic process and gave a new material with control structure and morphology. The electron microscopy (SEM and TEM) studies revealed that adding silica nanoparticles and Lotader in PA12 and PDMS phases, respectively, led to a drastic reduction in R v of the PDMS particles from 16.5 µm (virgin blend) to nearly 0.6 µm for the PA12/PDMS reactive blend. Therefore, a stable co‐continuous morphology was obtained for the new TPV based on 60–40 wt.‐% of PDMS‐PA12 blend. magnified image
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it