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Record W2126482788 · doi:10.1002/ejic.200890098

Coordination Chemistry of Neutral (L<i><sub>n</sub></i>)–Z Amphoteric and Ambiphilic Ligands (Eur. J. Inorg. Chem. 35/2008)

2008· article· en· W2126482788 on OpenAlexaff
Frédéric‐Georges Fontaine, Josée Boudreau, Marie‐Hélène Thibault

Bibliographic record

VenueEuropean Journal of Inorganic Chemistry · 2008
Typearticle
Languageen
FieldMaterials Science
TopicLanthanide and Transition Metal Complexes
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsChemistryLigand (biochemistry)DenticityMoietyLewis acids and basesStereochemistryCover (algebra)Lone pairCrystallographyOrganic chemistryMoleculeCrystal structure

Abstract

fetched live from OpenAlex

Abstract The cover picture shows a harlequin dancing in a room surrounded by transition metals. This character is a theatrical metaphor representing an ambiphilic ligand and its interaction with transition elements, which is the topic of the Microreview. The multiple arms describe the multidentate nature of this family of ligands. One side of his face is sad and represents the Lewis acid (Z) component of the ambiphilic ligand, while the other side is smiling and represents the L moiety, which is the donating component of the ligand. Details are presented by F.‐G. Fontaine et al. on p. 5439 ff. The artwork was designed by Marie Tremblay.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.939

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.188
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2008
Admission routes1
Has abstractyes

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