Thermodynamics of triaryltin chloride adduct complexes
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Bibliographic record
Abstract
The stability constants and the thermodynamic data were measured spectrophotometerically for 1:1 adduct formation of triaryltin chlorides, where aryl groups are p-chlorophenyl, phenyl, p-, m-, and o-tolyl, as Lewis acids, with chloride and bromide ions, as Lewis bases, in 50% v/v ethanol-water solvent. The stability constants and the thermodynamic parameters trend, confirmed the following softness trend of tin(IV) in the triaryltin chlorides:(p-, m-, o-tolyl) 3 SnCl > (phenyl) 3 SnCl > (p-chlorophenyl) 3 SnClKey words: tin(IV) complexes, thermodynamic parameters, mixed solvent, adduct formation.
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Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.009 | 0.000 |
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