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Modified BINOL Ligands in Asymmetric Catalysis

2003· review· en· 1,042 citations· W2126982344 on OpenAlex· 10.1021/cr020025b

Why is this work in the frame?

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian affiliationAn author listed a Canadian institution. This is the only route the usual frame has.
About CanadaIts subject is Canada, wherever its authors sit.

Full frame distilled prediction

Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

Candidate categories
Meta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categories
Insufficient payload (model declined to judge)
Domain
Candidate signal: noneConsensus signal: none
Study design
Candidate signal: Not applicableConsensus signal: none
Genre
Candidate signal: ReviewConsensus signal: Review
Teacher disagreement score
0.989
Threshold uncertainty score
1.000
Validation status
machine_predicted_unvalidated · codex-gemma-dda1882f352a

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0050.002
Bibliometrics0.0010.007
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.002

Machine scores (provisional)

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Opus teacher head0.070
GPT teacher head0.339
Teacher spread
0.269 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTModified BINOL Ligands in Asymmetric Catalysis†Yu Chen, Shahla Yekta, and Andrei K. YudinView Author Information Davenport Building, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6 Canada Cite this: Chem. Rev. 2003, 103, 8, 3155–3212Publication Date (Web):August 13, 2003Publication History Received20 February 2003Published online13 August 2003Published inissue 1 August 2003https://pubs.acs.org/doi/10.1021/cr020025bhttps://doi.org/10.1021/cr020025bresearch-articleACS PublicationsCopyright © 2003 American Chemical SocietyRequest reuse permissionsArticle Views14823Altmetric-Citations868LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Aldehydes,Catalysts,Ligands,Reaction products,Stereoselectivity Get e-Alerts

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

The record

Venue
Chemical Reviews
Topic
Asymmetric Hydrogenation and Catalysis
Field
Chemistry
Canadian institutions
University of Toronto
Funders
not available
Keywords
CitationGeorge (robot)ChemistryLibrary scienceSocial mediaInformation retrievalComputer scienceWorld Wide WebNanotechnologyArtificial intelligenceMaterials science
Has abstract in OpenAlex
yes