Cyclic Voltammetry of Zn/Zn(II) Couple in Dycyanamide Anion and Bis-(trifluoromethylsulfonyl)Imide Anion Based Ionic Liquids
Bibliographic record
Abstract
The electrochemistry of a Zn/Zn(II) couple was studied and compared in four kinds of room temperature ionic liquids (RTILs) (1-butyl-1-methylpyrrolidinium dicyanamide (BMP-DCA), 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMI-TFSI), 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (BMP-TFSI) and 1-methyl-1-pentylpyrrolidinium bis(trifluoromethanesulfonyl)imide (MPP-TFSI)), with the aim of screening desirable RTILs as replacements for traditional aqueous electrolytes for Zn rechargeable batteries. Cyclic voltammetry was used to study the reversibility and cyclability of Zn redox in each RTIL. The morphology of Zn deposits prepared from each RTIL was characterized by scanning electron microscopy. The results show that Zn redox has the best cyclability in the DCA-based RTIL, with the Zn deposit morphology characterized by finely dispersed rods composed of granular Zn particles (~50-100 nm in size). In TFSI-based ionic liquids, the Zn/Zn(II) couple reaction had a higher current density than that in the DCA-based ionic liquid, implying different electron transfer processes. BMP-DCA and EMI-TFSI are promising RTILs worthy of further investigation.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".