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Record W2127569233 · doi:10.1002/pen.21732

A UV‐initiated reactive extrusion process for production of controlled‐rheology polypropylene

2010· article· en· W2127569233 on OpenAlexafffund
Guangjian He, Costas Tzoganakis

Bibliographic record

VenuePolymer Engineering and Science · 2010
Typearticle
Languageen
FieldMaterials Science
TopicPolymer crystallization and properties
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsReactive extrusionMaterials sciencePolypropylenePhotoinitiatorPlastics extrusionExtrusionRheologyComposite materialPolymerDifferential scanning calorimetryUltravioletFourier transform infrared spectroscopyChemical engineering

Abstract

fetched live from OpenAlex

Abstract A new reactive extrusion process for the production of controlled‐rheology polypropylene (CRPP) has been developed. Instead of the traditionally used peroxides, this process employs a photoinitiator and an ultraviolet (UV) lamp. Experiments have been carried out in a corotating intermeshing twin‐screw extruder in which after mixing of the photoinitiator with the polypropylene, the melt stream is irradiated for just several seconds over two open barrel sections. Benzophonene (BP) has been used as the initiator and the effects of initiator concentration, polymer flow rate, and reaction temperature have been studied. The CRPP produced have been characterized through rheological measurements, size exclusion chromatography, differential scanning calorimetry, and Fourier transform infrared spectroscopy. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.329

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.257
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations27
Published2010
Admission routes2
Has abstractyes

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