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Record W2128181668 · doi:10.1002/mren.201100007

Residence Time Distribution Study of a Living/Controlled Radical Miniemulsion Polymerization System in a Continuous Tubular Reactor

2011· article· en· W2128181668 on OpenAlexaff
Thomas E. Enright, Michael F. Cunningham

Bibliographic record

VenueMacromolecular Reaction Engineering · 2011
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsQueen's UniversityXerox (Canada)
Fundersnot available
KeywordsResidence time distributionMiniemulsionTRACERPlug flowResidence time (fluid dynamics)Dispersion (optics)Materials sciencePolymerFlow (mathematics)MonomerAqueous solutionPlug flow reactor modelPolymerizationChemical engineeringPolymer chemistryThermodynamicsChemistryContinuous stirred-tank reactorMechanicsComposite materialPhysical chemistryOpticsNuclear physics

Abstract

fetched live from OpenAlex

Abstract Residence time distribution (RTD) studies were done to determine the flow characteristics in a continuous tubular reactor. Pulse tracer experiments were done at different flow rates and temperatures, and a comparison was made between a homogeneous aqueous salt mixture versus a heterogeneous miniemulsion mixture. The heterogeneous system was studied under two different conditions, one with a monomer‐in‐water droplet dispersion and one with fully formed polymer particles dispersed in water. There were differences observed between all of the systems tested and none of them matched an ideal plug flow condition. The reactor contains stagnant zones of varying volume and tracer spreading was observed in all cases. The dispersion model was found to model the system quite well in most cases. magnified image

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.040
Threshold uncertainty score0.987

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.188
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2011
Admission routes1
Has abstractyes

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