The Cross‐Dehydrogenative Coupling of CH Bonds: A Versatile Strategy for CC Bond Formations
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Abstract
Over the last decade, substantial research has led to the introduction of an impressive number of efficient procedures which allow the selective construction of CC bonds by directly connecting two different CH bonds under oxidative conditions. Common to these methodologies is the generation of the reactive intermediates in situ by activation of both CH bonds. This strategy was introduced by the group of Li as cross-dehydrogenative coupling (CDC) and discloses waste-minimized synthetic alternatives to classic coupling procedures which rely on the use of prefunctionalized starting materials. This Review highlights the recent progress in the field of cross-dehydrogenative C sp 3C formations and provides a comprehensive overview on existing procedures and employed methodologies.
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The record
- Venue
- Angewandte Chemie International Edition
- Topic
- Catalytic C–H Functionalization Methods
- Field
- Chemistry
- Canadian institutions
- McGill UniversityCentre in Green Chemistry and Catalysis
- Funders
- —
- Keywords
- BondCoupling (piping)Combinatorial chemistryChemistryNanotechnologyComputer scienceMaterials scienceEngineeringBusinessMechanical engineering
- Has abstract in OpenAlex
- yes