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Record W2129357492 · doi:10.1002/anie.200701117

Forming Aromatic Hemispheres on Transition‐Metal Surfaces

2007· article· en· W2129357492 on OpenAlex
Kwang Taeg Rim, Mohamed Siaj, Shengxiong Xiao, Matthew Myers, Vincent Carpentier, Li Liu, Chaochin Su, Michael L. Steigerwald, Mark S. Hybertsen, Peter H. McBreen, George W. Flynn, Colin Nuckolls

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie International Edition · 2007
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Chemical Physics Studies
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsChirality (physics)Transition metalMetalRutheniumSurface (topology)Crystal (programming language)CrystallographyCarbon fibersMaterials scienceChemistryNanotechnologyChemical physicsPhysicsComputer scienceOrganic chemistryComposite materialGeometryCatalysisMetallurgyNuclear physicsMathematics

Abstract

fetched live from OpenAlex

Bowled over: Hexabenzocoronene (HBC) binds to the surface of a ruthenium crystal through its “radialene” π bonds. Measurements on the product after heating of the HBC–surface complex are consistent with a bowl-shaped molecular fragment that is strongly bound, rim down, to the metal surface. This structure represents a new type of seed that could be used to grow single-walled carbon nanotubes of specific diameter and chirality.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.253
Threshold uncertainty score0.599

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.265
Teacher spread0.253 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it