MétaCan
Menu
Back to cohort
Record W2130436945 · doi:10.3749/canmin.45.6.1535

THE SYSTEM Cu-Rh-S AT 900 , 700 , 540  AND 500 C

2007· article· en· W2130436945 on OpenAlexvenueno aff
Sven Karup-Møller, Emil Makovicky

Bibliographic record

VenueThe Canadian Mineralogist · 2007
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMineralogy and Gemology Studies
Canadian institutionsnot available
Fundersnot available
KeywordsSolubilityTernary operationRhodiumSulfidePhase (matter)Copper sulfideTernary numeral systemChemistryCopperMetallurgyMaterials scienceInorganic chemistryAnalytical Chemistry (journal)CatalysisPhysical chemistryEnvironmental chemistry

Abstract

fetched live from OpenAlex

Phase relations in the dry condensed system Cu–Rh–S were determined at 900, 700, 540 and 500°C. At 900°C, the system contains digenite, four rhodium sulfides (Rh 17 S 15 , Rh 3 S 4 , Rh 2 S 3 and RhS ~3 ), three ternary sulfides (CuRh 2 S 4 , Cu x RhS 3+ x and a fibrous sulfide in the range Cu 11.9 Rh 24.6 S 63.6 – Cu 20.4 Rh 19.8 S 59.7 ), Cu–S sulfide melt, and Cu–Rh alloys. At 700°C, the ternary association changes to CuRh 2 S 4 , CuRhS 3 , and CuRhS 4 . All these phases persist with little change at 540°C. At 500°C, CuS appears, and the number of phases is reduced; only CuRhS 4 persists as a ternary phase. Ranges of solid solution for Cu–Rh alloys drop drastically with temperature. The solubility of Cu in Rh sulfides increases moderately as temperature decreases from 900° to 540°C. The solubility of Rh in digenite and Cu–S melt is very limited at all temperatures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.398
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0030.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.196
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2007
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian MineralogistSame topicMineralogy and Gemology StudiesFrench-language works237,207