Calculation of solubilities of the pesticides diuron and monuron in organic nonelectrolyte solvents using UNIFAC and modified UNIFAC (dortmund) models
Bibliographic record
Abstract
Abstract The solubility of diuron (3‐(3,4‐dichlorophenyl)‐1, 1 ‐dimethyl urea) and monuron (3‐(4‐chlorophenyl)‐1, 1 ‐dimethyl urea) in 49 and 43 different organic non‐electrolyte solvents, respectively, have been calculated. It was found that Modified UNIFAC described well the solubilities both in polar solvents like alcohols, ketones, esters and ethers and in nonpolar solvents like alkanes and aromatic hydrocarbons. UNIFAC and the mobile order theory supplement each other well in calculating the solubilities, which means that one can choose the right model depending on the solvent one is using.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".