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Record W2131607077 · doi:10.1139/a01-013

Inputs and outputs of mercury from terrestrial watersheds: a review

2002· review· en· W2131607077 on OpenAlexvenueno aff
D. F. Grigal

Bibliographic record

VenueEnvironmental Reviews · 2002
Typereview
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsnot available
Fundersnot available
KeywordsEnvironmental scienceFlux (metallurgy)MethylmercuryThroughfallWatershedMercury (programming language)StreamflowHydrology (agriculture)Surface runoffBiogeochemical cycleWetlandEnvironmental chemistrySoil waterChemistryEcologySoil scienceDrainage basin

Abstract

fetched live from OpenAlex

This review focuses on mercury (Hg) inputs and outputs in temperate and boreal terrestrial systems. It covers deposition via throughfall and litterfall, whose sum (ca. 38 µg m –2 a –1 ) is greater than that via precipitation (ca. 10 µg m –2 a –1 ). Outputs considered include volatilization, soil sequestration, and streamflow. The former is highly uncertain, but the mean rate (11 ng m –2 h –1 ) over a growing season is equivalent to about 32 µg m –2 a –1 . Modern rates of soil sequestration (ca. 5 µg m –2 a –1 ) and streamflow fluxes (ca. 2 µg m –2 a –1 ) balance the annual budget. The majority of the uncertainty in the budget is related to volatilization. Nonetheless, a large fraction of atmospheric Hg is likely a product of continuing deposition and volatilization. Watershed characteristics related to streamflow fluxes of both Hg and methylmercury (MeHg) are discussed. Both runoff concentration and flux of Hg are weakly and inversely related to watershed size. Dissolved organic carbon (DOC) and particulates are important carriers of Hg; watershed activities that affect either affect Hg flux. Runoff flux of MeHg is skewed with about 80% of observations less than 0.15 µg m –2 a –1 . Although there is no pattern of MeHg flux with watershed size, there is a strong positive relationship between flux and wetland area. Wetlands are a site of MeHg production and their presence increases water residence time; both increase MeHg flux. Concentrations of MeHg in streamflow from watersheds with wetlands are near the current water quality criterion, and effective control measures in those watersheds appear problematic.Key words: deposition, non-point pollution, methylmercury, wetlands, dissolved organic carbon (DOC).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.004
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.066
GPT teacher head0.309
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations461
Published2002
Admission routes1
Has abstractyes

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