Preparation of crosslinked microspheres and porous solids from hydrocarbon solutions: A new variation of precipitation polymerization chemistry
Bibliographic record
Abstract
Abstract A new variation of precipitation polymerization is described wherein CH bond addition to a triallyl monomer contributes to molecular weight growth, thereby incorporating a significant amount of saturated hydrocarbon into the solid phase. The extent of monomer oligomerization relative to hydrocarbon addition is shown to increase with the concentration of allyl benzoate in cyclooctane. An extension to the trifunctional monomer, triallyl trimesate, results in phase separation of hydrocarbon‐monomer adducts to give a dispersed phase whose continued reactivity leads to crosslinked microspheres. The relationships between reaction conditions and solid‐phase composition and morphology are discussed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6561–6570, 2009
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".