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Record W2133355382 · doi:10.1002/aic.690491124

Regular solution model for asphaltene precipitation from bitumens and solvents

2003· article· en· W2133355382 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueAIChE Journal · 2003
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsUniversity of Calgary
FundersNatural Sciences and Engineering Research Council of CanadaSyncrude
KeywordsAsphalteneMolar massSolubilityChemistryMolarMolar volumeHildebrand solubility parameterMole fractionPrecipitationSolventAlkaneMolar concentrationThermodynamicsMolar mass distributionFraction (chemistry)ChromatographyHydrocarbonOrganic chemistryPhysical chemistryGeologyPolymer

Abstract

fetched live from OpenAlex

Abstract A regular solution theory liquid‐liquid equilibrium model was developed to predict asphaltene precipitation from Western Canadian bitumens. The input parameters for the model are the mole fraction, molar volume, and solubility parameters for each component. Bitumens were divided into four main pseudo‐components corresponding to SARA fractions: saturates, aromatics, resins, and asphaltenes. Asphaltenes were divided into fractions of different associated molar mass based on a Schultz‐Zimm molar mass distribution. Asphaltene self‐association was accounted for through the average molar mass of the distribution. The molar volumes and solubility parameters of the pseudo‐components were calculated using solubility, density, and molar mass measurements. The model successfully predicted the effect of solvent type and associated molar mass on asphaltene precipitation for model oil and n‐alkane systems. The model also predicted the onset and amount of asphaltene precipitation from bitumens.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.844
Threshold uncertainty score0.341

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.258
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it