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Record W2133577023 · doi:10.1098/rsbm.2009.0007

Donald Allan Ramsay CM. 11 July 1922 — 25 October 2007

2009· article· en· W2133577023 on OpenAlexaffabout
W.F. Davidson, A. R. W. McKellar

Bibliographic record

VenueBiographical Memoirs of Fellows of the Royal Society · 2009
Typearticle
Languageen
FieldChemistry
TopicMolecular Spectroscopy and Structure
Canadian institutionsSteacie Institute for Molecular SciencesNational Research Council Canada
Fundersnot available
KeywordsMolecular spectroscopySpectroscopyWork (physics)OriginalityFlash photolysisPhysicsLawPolitical scienceAstronomyQuantum mechanics

Abstract

fetched live from OpenAlex

Donald Allan Ramsay made significant contributions to the study of molecular spectra and molecular structure during a 60-year career at the Sussex Drive Laboratories of the National Research Council of Canada. He was an early pioneer in the technique of flash photolysis, or kinetic spectroscopy, opening new vistas in generating the spectra of unstable free radical molecules and probing their dynamics. His work on the amidogen radical, NH 2 , provided the first example of the Renner–Teller effect in molecular spectroscopy, resulting from interactions between electronic and vibration–rotational motions. He was one of the best-known figures in the field of molecular spectroscopy. Travelling widely, he had abundant and productive collaborations with scientists from all around the world. His seminal publications are a true indication of the energy, insight and originality that he applied to his scientific work.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.212
Threshold uncertainty score0.708

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0010.001
Scholarly communication0.0020.001
Open science0.0010.002
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.2120.133

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.218
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2009
Admission routes2
Has abstractyes

Explore more

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