Vibrational dependence of the rotational, spin-orbit splitting, and lambda-doubling parameters in the <i>C</i>″<sup>5</sup>Π<i><sub>ui</sub></i> state of N<sub>2</sub> This article is part of a Special Issue on Spectroscopy at the University of New Brunswick in honour of Colan Linton and Ron Lees.
Bibliographic record
Abstract
We have recorded the high-resolution emission spectrum of the Herman infrared band (C″ 5 Π ui –A′ 5 Σ g + ) system of N 2 in the 8000–15000 cm –1 range from an experimental set-up coupling a corona discharge with a supersonic expansion. The analysis of four new bands has permitted us to determine spectroscopic parameters of the v′ = 0 and v′ = 1 vibrational levels of the C″ 5 Π ui state and to study the vibrational dependence of the molecular parameters over the range v′ = 0 to v′ = 4. In particular, the values of the spin-orbit coupling and the Λ–doubling parameters are discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".