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Record W2135416889 · doi:10.1093/clinchem/48.12.2261

Hemoglobin Wayne in a British Family: Identification by Electrospray Ionization/Mass Spectrometry

2002· article· en· W2135416889 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueClinical Chemistry · 2002
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicHemoglobin structure and function
Canadian institutionsnot available
Fundersnot available
KeywordsElectrospray ionizationMass spectrometryHemoglobinChromatographyIdentification (biology)ChemistryBiologyBiochemistry

Abstract

fetched live from OpenAlex

Hemoglobin (Hb) Wayne (an elongated α-chain frameshift variant that exists as 2 forms, Hb Wayne Asn and Hb Wayne Asp) was first described in 1976 in a Caucasian neonate in Pike County, Central Georgia, whose grandparents originated from Birmingham, Alabama (1). Two other families have been reported, one a Caucasian family from Michigan (2), and the other from Canada (3). Clinically, Hb Wayne leads to an increased oxygen affinity Hb with noncooperativity and a markedly reduced Bohr effect. Hb Wayne Asn and Hb Wayne Asp exhibit differences in their carbon monoxide-binding properties (4). We report the identification of Hb Wayne in a 28-year- old Caucasian diabetic female patient whose blood was undergoing analysis for glyco-Hb. Her initial pathologic investigations showed no abnormalities (144 g/L Hb; erythrocytes, 5.09 × 1012/L; packed cell volume, 0.437 L/L; mean cell volume, 85.8 fL; mean cell Hb, 28.3 pg; mean cell Hb concentration, 330 g/L). Analysis of a hemolysate for glyco-Hb using a HA-8140 analyzer (Menarini Diagnostics Ltd.) revealed a slight shoulder on the glycated Hb peak with …

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.017
Threshold uncertainty score0.854

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.262
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it