Temporal evolution of an ultrathin, noncrystalline ice deposit at crystallization near 160 K studied by FT-IR reflection-absorption spectroscopy
Bibliographic record
Abstract
The temporal evolution of the OH stretching modes of a noncrystalline ice deposit upon annealing followed by crystallization near 160 K has been investigated by FT-IR reflectionabsorption spectroscopy. Using the earlier theoretical results from Whalley (E. Whalley. Can. J. Chem. 55, 3429 (1977)) and from Buch and Devlin (V. Buch and J.P. Devlin. J. Chem. Phys. 110, 3437 (1999)), the most prominent changes in these modes have been characterized for the first time. A dynamical picture of the structural transformation during crystallization has been developed, and it supports the observation that crystallization proceeds directly from a noncrystalline to a crystalline state without any long-lived intermediate state structurally different from its noncrystalline predecessor.Key words: crystallization, noncrystalline ice, FT-IR reflectionabsorption spectroscopy, temporary evolution.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".