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Record W2135684168 · doi:10.1002/chem.200901371

Sensitized Ce<sup>3+</sup> and Gd<sup>3+</sup> Ultraviolet Emissions by Tm<sup>3+</sup> in Colloidal LiYF<sub>4</sub> Nanocrystals

2009· article· en· W2135684168 on OpenAlexafffund
Venkataramanan Mahalingam, Rafik Naccache, Fiorenzo Vetrone, John A. Capobianco

Bibliographic record

VenueChemistry - A European Journal · 2009
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsConcordia University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPhoton upconversionUltravioletNanocrystalExcitationRare earthIonDopingMaterials scienceAnalytical Chemistry (journal)PhysicsChemistryRadiochemistryNanotechnologyOptoelectronicsMineralogyEnvironmental chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

I see UC UV! Gd3+/Tm3+/Yb3+- and Ce3+/Tm3+/Yb3+-doped LiYF4 nanocrystals are capable of generating UV, visible, and NIR upconversion (UC) emissions following λ=980 nm excitation (see figure). Gd3+ and Ce3+ can be sensitized by the Tm3+ ion, which results in UV upconversion in the region of λ=280–340 nm, making them attractive as biological probes or novel scintillating materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0000.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.215
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations65
Published2009
Admission routes2
Has abstractyes

Explore more

Same venueChemistry - A European JournalSame topicLuminescence Properties of Advanced MaterialsFrench-language works237,207