Efficient Surface-Relief Gratings in Hydrogen-Bonded Polymer−Azobenzene Complexes
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Bibliographic record
Abstract
We show that efficient photoinduced surface-relief gratings can be inscribed in polymer-azobenzene complexes which are bonded by phenol-pyridine hydrogen bonding. The grating inscription was studied as a function of chromophore concentration and the molecular weight of the host polymer, both of which can be easily tuned without demanding organic synthesis. Stable gratings with modulation depth as high as 440 nm and with diffraction efficiency exceeding 40% were inscribed in the equimolar complexes. Our results demonstrate that phenol-pyridine hydrogen bonding not only allows one to increase the chromophore content until each polymer unit is occupied but is also sufficiently strong to induce mass migration of the polymer chains in a manner comparable to covalently functionalized polymers.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it