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Record W2137925106 · doi:10.1002/anie.201006223

Self‐Seeding in One Dimension: An Approach To Control the Length of Fiberlike Polyisoprene–Polyferrocenylsilane Block Copolymer Micelles

2011· article· en· W2137925106 on OpenAlexaff
Jieshu Qian, Gérald Guérin, Yijie Lu, Graeme Cambridge, Ian Manners, Mitchell A. Winnik

Bibliographic record

VenueAngewandte Chemie International Edition · 2011
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMicelleCrystallinityCopolymerSeedingMaterials sciencePolymerDissolutionDecaneChemical engineeringPolymer chemistryChemical physicsCrystallographyChemistryComposite materialThermodynamicsPhysicsAqueous solutionPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Do it yourself: When short fragments (ca. 50 nm) of rodlike PI-PFS block copolymer micelles in decane are heated above a characteristic temperature (60 °C) and then cooled to room temperature, a smaller number of longer micelles with a narrow length distribution are obtained. This process resembles self-seeding of polymer crystals, involving selective dissolution of the fragments of the lowest degree of crystallinity with the surviving submicroscopic seeds acting as nuclei for the growth of micelles upon cooling.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.230
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations165
Published2011
Admission routes1
Has abstractyes

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