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Record W2139294940 · doi:10.1002/cjce.5450780106

Coprecipitation of CaCO<sub>3</sub> and CaSO<sub>4</sub>

2000· article· en· W2139294940 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2000
Typearticle
Languageen
FieldMaterials Science
TopicCalcium Carbonate Crystallization and Inhibition
Canadian institutionsnot available
Fundersnot available
KeywordsCoprecipitationPrecipitationSalt (chemistry)CrystallizationChemistryGypsumKineticsInorganic chemistryMineralogyMaterials sciencePhysical chemistryMetallurgyMeteorologyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Coprecipitation characteristics of CaCO 3 and CaSO 4 were studied under various operating conditions. The investigations were carried out in temperature‐controlled batch tests. Coprecipitation results were compared with our experimental results of a single salt crystallization. It was found that the induction period and kinetics of coprecipitation of these two salts follow that of pure CaCO 3 . However, thermodynamic concentrations of Ca in coprecipitation followed that of pure CaSO 4 at all times. The relationship between the thermodynamic concentrations of Ca for pure CaCO 3 and CaSO 4 solutions depended on the pH of the CaCO 3 solution. CaSO 4 precipitated in form of gypsum and had a needle shape structure; CaCO 3 had a spiral growth and precipitated in form of calcite. The precipitate structure was affected by the co‐existence of salts; the co‐precipitation resulted in CaCO 3 crystals interwoven by CaSO 4 crystals. This tends to result in a co‐precipitate that is stronger than pure CaSO 4 and weaker than pure CaCO 3 precipitate.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.348

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.183
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it