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Record W2142232123 · doi:10.3749/canmin.47.3.573

CONDENSATE MINERALS FROM A BURNING COAL-WASTE HEAP IN AVION, NORTHERN FRANCE

2009· article· en· W2142232123 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Mineralogist · 2009
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicCoal and Its By-products
Canadian institutionsnot available
Fundersnot available
KeywordsHeap (data structure)CoalGeologyGeochemistryArchaeologyMining engineeringMineralogyGeographyMathematics

Abstract

fetched live from OpenAlex

A coal-waste heap in Avion, northern France, that has been undergoing subsurface combustion for several decades, is marked by the occurrence of efflorescences at combustion sites where gas and water vapor escape from surficial cracks and vents. Analysis of the efflorescences show that twenty different species of mineral are present, comprising various sulfates, as well as halides and native sulfur. The constituents needed for the formation of these minerals are ultimately derived from the heap of coal-mine waste, composed mainly of pyrite-bearing carbonaceous shale, coal and minor amounts of sandstone. They may be partly released by acid weathering of waste-heap materials prior to combustion, but largely by thermal decomposition and oxidation of those materials during combustion processes. Formation of the efflorescences near gas-discharge zones indicates transport of constituent to those zones from the inner part of the waste heap, which can occur in the gas phase for some elements (S, N, H and Cl), but would require droplets of water vapor as carriers for most cations. Interaction between condensate solutions and the local debris at the surface of the waste heap may also contribute to cations input prior to the formation of secondary minerals. Most minerals formed from a liquid phase along the rock-debris surface at low temperatures (T ≤ 100°C), as confirmed by the occurrence of fluid inclusions. Only salammoniac, native sulfur and mascagnite (where crystallized as a monocrystalline phase) were formed directly from a gas phase. The coal-waste heap shows great variations in mineral assemblages among sampling sites, which must be related to variations in waste composition and in conditions at the level at which the elements are released and where mineral formation takes place.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.086
Threshold uncertainty score0.775

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.201
Teacher spread0.184 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it