Radical Copolymerization of a Phosphaalkene with Styrene: New Phosphine‐Containing Macromolecules and Their Use in Polymer‐Supported Catalysis
Why this work is in the frame
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Bibliographic record
Abstract
PC bonds mimic CC bonds in the radical-initiated copolymerization of a phosphaalkene 1 and styrene (see scheme). The resulting copolymers 2 have unprecedented phosphine-containing backbones with phosphorus compositions that vary depending on the monomer ratios. These novel functional hybrid inorganic–organic macromolecules are used as polymeric supports for the Pd-catalyzed Suzuki coupling. VAZO=1,1′-azobis(cyclohexanecarbonitrile).
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it