Electrocatalytic oxidation and flow amperometric detection of hydrazine on a dinuclear ruthenium phthalocyanine-modified electrode
Bibliographic record
Abstract
Electrocatalytic oxidation of hydrazine on a dinuclear ruthenium phthalocyanine ((RuPc)2) modified electrode was studied using cyclic voltammetry (CV) and rotating disc electrode (RDE) techniques. At pH = 13, a four-electron oxidation of hydrazine to N2 was observed. A suitable mechanism was proposed by analyzing the rate equation and the Tafel slope. The flow injection analysis was performed to characterize the (RuPc)2-modified electrode as an amperometric sensor for the detection of hydrazine. The electrode displays an excellent accuracy and precision in phosphate solution at pH 12 and 13. The linearity range was from 30 nM to 1 mM with a correlation coefficient of 0.9998.Key words: ruthenium phthalocyanine, electrocatalysis, surface-modified electrode, hydrazine, amperometric sensor.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".