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Record W2143475103 · doi:10.1149/1.2953509

Stabilization and Characterization of Pt Nanoparticles on HOPG

2008· article· en· W2143475103 on OpenAlexaff
Helga C. Halvorsen, Christina Bock, B. MacDougall, Dashan Wang

Bibliographic record

VenueECS Transactions · 2008
Typearticle
Languageen
FieldEngineering
TopicSemiconductor materials and devices
Canadian institutionsNational Research Council Canada
FundersIndustrial Technology Research InstituteNational Science Council
KeywordsHighly oriented pyrolytic graphiteCatalysisMaterials sciencePlatinumPyrolytic carbonChemical engineeringElectrochemistryCarbon monoxideThermal decompositionSubstrate (aquarium)NanoparticleThermal stabilityPlatinum nanoparticlesNanotechnologyScanning tunneling microscopeChemistryPyrolysisPhysical chemistryElectrodeOrganic chemistry

Abstract

fetched live from OpenAlex

Platinum nano-catalysts are deposited, either by electrodeposition at constant potential or thermal decomposition, onto highly ordered pyrolytic graphite (HOPG). To help stabilize the nano-catalyst, the HOPG substrate is oxidized either by electrochemical methods or by ozone gas. The combination of two deposition techniques and two substrate oxidation techniques results in four different types of samples. As a point of reference, the particle morphology, activity towards oxidation of adsorbed carbon monoxide, and electrochemical stability of the four different types of samples are compared to a sample made by electrodeposition of Pt onto freshly cleaved HOPG. Of the four samples prepared, the combination of thermal reduction onto ozone oxidized HOPG was found to produce the most stable platinum nano-catalyst.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.019
Threshold uncertainty score0.191

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.192
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2008
Admission routes1
Has abstractyes

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