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Record W2144094904 · doi:10.1002/anie.200790067

Cover Picture: Template‐Directed Synthesis of a π‐Conjugated Porphyrin Nanoring (Angew. Chem. Int. Ed. 17/2007)

2007· paratext· en· W2144094904 on OpenAlexaboutno aff
Markus Hoffmann, Craig J. Wilson, Barbara Odell, Harry L. Anderson

Bibliographic record

VenueAngewandte Chemie International Edition · 2007
Typeparatext
Languageen
FieldMaterials Science
TopicPorphyrin and Phthalocyanine Chemistry
Canadian institutionsnot available
Fundersnot available
KeywordsNanoringPorphyrinCover (algebra)OligomerConjugated systemRing (chemistry)TemplateNanotechnologyChemistryMaterials sciencePolymer scienceCrystallographyPolymer chemistryPolymerEngineeringPhotochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

A molecular wire is forged into a smooth ring—not by the blacksmith's fire, as shown in the background of the picture—but by the vicelike grip of an octadentate template. H. L. Anderson and co‐workers describe in their Communication on page 3122 ff. how a linear porphyrin oligomer can be cyclized to generate a highly symmetric belt‐shaped π system (image by M. Hoffmann; background photograph by J. McNerney, Yukon Forge, www.yukonforge.com).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.381
Threshold uncertainty score0.883

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.3810.103

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.266
Teacher spread0.253 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2007
Admission routes1
Has abstractyes

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