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Record W2145860243 · doi:10.1107/s1600536802019153

Bis[di-η<sup>5</sup>-cyclopentadienylcobalt(I)] dicarbonyltrichloro(chlorodiphenylsilyl)ruthenium(II)

2002· article· en· W2145860243 on OpenAlexaff
A. Berenbaum, Alan J. Lough, Ian Manners

Bibliographic record

VenueActa Crystallographica Section E Structure Reports Online · 2002
Typearticle
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsRutheniumChemistryOctahedronCrystallographyAtom (system on chip)Bond lengthStereochemistryGroup (periodic table)Medicinal chemistryCrystal structureCatalysis

Abstract

fetched live from OpenAlex

The asymmetric unit of the title compound, [Co(C5H5)2]2[RuCl3(C12H10ClSi)(CO)2], consists of a discrete ClPh2SiRu(CO)2Cl3 dianion and two (η-C5H5)2Co cations. The dianion has octahedral coordination geometry, with the three Cl atoms in cis positions. In addition, two carbonyl groups (cis) and a Ph2ClSi group (bonded through Si) complete the coordination. The Ru—Si bond length is 2.362 (3) Å and the longest Ru—Cl bond [2.566 (2) Å] is trans to the Si atom. In one cobaltocene cation, the cyclo­penta­dienyl (Cp) rings are staggered, while in the other, the Cp rings are almost eclipsed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.948
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.239
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2002
Admission routes1
Has abstractyes

Explore more

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