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Record W2146206607 · doi:10.1021/ja046050b

Vibration−Rotation Emission Spectra of Gaseous ZnH<sub>2</sub> and ZnD<sub>2</sub>

2004· article· en· W2146206607 on OpenAlexaff
Alireza Shayesteh, Dominique Appadoo, Iouli E. Gordon, P. F. Bernath

Bibliographic record

VenueJournal of the American Chemical Society · 2004
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Chemical Physics Studies
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsChemistrySpectral lineEmission spectrumInfraredAntisymmetric relationInfrared spectroscopyRotation (mathematics)Analytical Chemistry (journal)Fourier transform infrared spectroscopyHigh resolutionFourier transformAtomic physicsOpticsPhysics

Abstract

fetched live from OpenAlex

Gaseous ZnH 2 and ZnD 2 have been discovered in an emission source that combines an electrical discharge with a high-temperature furnace. High-resolution infrared emission spectra of ZnH 2 and ZnD 2 have been recorded with a Fourier transform spectrometer, and the antisymmetric stretching fundamental bands of 64 ZnH 2 and 64 ZnD 2 were detected near 1889.4 and 1371.6 cm -1, respectively. Rotational analysis of the bands yielded r 0 bond distances of 1.535 271(1) and 1.531 836(9) Å for linear 64 ZnH 2 and 64 ZnD 2, respectively.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.035
Threshold uncertainty score0.603

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.229
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations43
Published2004
Admission routes1
Has abstractyes

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