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Record W2149882032 · doi:10.1039/c4ta02135e

A novel electroactive hybrid film electrode with proton buffer effect for detecting hydrogen peroxide and uric acid

2014· article· en· W2149882032 on OpenAlexaff
Zhongde Wang, Yang Ma, Xiaogang Hao, Wei Huang, Guoqing Guan, Abuliti Abudula, Hui Zhang

Bibliographic record

VenueJournal of Materials Chemistry A · 2014
Typearticle
Languageen
FieldEngineering
TopicElectrochemical sensors and biosensors
Canadian institutionsWestern University
Fundersnot available
KeywordsMaterials scienceCyclic voltammetryCarbon nanotubeScanning electron microscopeElectrodeFourier transform infrared spectroscopyHydrogen peroxideTransmission electron microscopyDetection limitBuffer solutionAnalytical Chemistry (journal)Nuclear chemistryElectrochemistryChemical engineeringNanotechnologyChemistryComposite materialOrganic chemistryChromatography

Abstract

fetched live from OpenAlex

In this study, a novel hybrid film electrode with proton buffer effect for the detection of hydrogen peroxide (H2O2) and uric acid (UA) was fabricated by a facile one-step electrosynthesis method using cyclic voltammetry (CV). The electrode was composed of a nickel hexacyanoferrate cubic nanoparticle (NiHCNP) inlaid poly(neutral-red) (PN) film formed on carbon nanotube-(CNTs) modified glassy carbon (GC) plate. PN in the hybrid film was found to not only act as a proton buffer, which can receive and release protons to meet the demands of electrocatalytic reaction, but also to anchor NiHCNP on the surface of CNTs and stabilize NiHCNP. The morphology and structure of the as-prepared NiHCNP/PN/CNTs hybrid film was characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrum (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The prepared hybrid film electrodes showed excellent electrocatalytic activity with high sensitivity, fast response time and low detection limit for the detection of H2O2 as well as UA.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.181
Teacher spread0.178 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2014
Admission routes1
Has abstractyes

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Same venueJournal of Materials Chemistry ASame topicElectrochemical sensors and biosensorsFrench-language works237,207