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Record W2151186887 · doi:10.1149/1.3467837

Condensation in PEM Fuel Cell Gas Diffusion Layers: A Pore Network Modeling Approach

2010· article· en· W2151186887 on OpenAlexafffund
James Hinebaugh, Aimy Bazylak

Bibliographic record

VenueJournal of The Electrochemical Society · 2010
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Toronto
KeywordsCoalescence (physics)NucleationSaturation (graph theory)Gaseous diffusionCondensationProton exchange membrane fuel cellElectrolyteCapillary actionChemistryPorous mediumPorosityChemical physicsChemical engineeringThermodynamicsMaterials scienceMembraneComposite materialPhysical chemistry

Abstract

fetched live from OpenAlex

A two-dimensional dynamic pore network model is developed and employed to simulate the through-plane transport of liquid water originating from condensation in hydrophobic gas diffusion layers (GDLs) for polymer electrolyte membrane (PEM) fuel cells. The model tracks viscous and capillary forces over a range of specified condensation rates and nucleation positions. A simplified mass transport assumption of a uniform water vapor flux between the cathode catalyst layer and the liquid water cluster allows for a computationally inexpensive model. Stochastically generated steady-state saturation profiles are compared to investigate the effects of nucleation position, channel rib presence, coalescence assumptions, and condensation rates on liquid water distribution. Results indicate that GDL saturation conditions become increasingly more desirable as nucleation sites are placed further away from the catalyst layer, and saturation profiles are significantly higher when nucleation is adjacent to a hydrophobic rib compared to the gas channel or a hydrophilic rib. Meanwhile, the trapping assumption that affects liquid water coalescence in small throats has little impact on saturation patterns but has a large impact on the system's viscous forces. Finally, the model can predict the limiting water cluster growth rates of capillary dominated growth for a given pore network.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.839
Threshold uncertainty score0.437

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.178
Teacher spread0.173 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations49
Published2010
Admission routes2
Has abstractyes

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