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Record W2151828910 · doi:10.1002/cjce.22074

Effect of surfactant on the dynamics of a crude oil droplet in water column: Experimental and numerical investigation

2014· article· en· W2151828910 on OpenAlexvenueno aff
Abhijit Rao, Rupesh K. Reddy, Franz S. Ehrenhauser, K. Nandakumar, Louis J. Thibodeaux, Dandina N. Rao, Kalliat T. Valsaraj

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2014
Typearticle
Languageen
FieldEngineering
TopicFluid Dynamics and Heat Transfer
Canadian institutionsnot available
FundersGulf of Mexico Research Initiative
KeywordsSurface tensionPulmonary surfactantNozzleOil dropletMechanicsVolume of fluid methodComputational fluid dynamicsVolume (thermodynamics)ChemistryMaterials scienceChromatographyThermodynamicsPhysicsFlow (mathematics)Emulsion

Abstract

fetched live from OpenAlex

Abstract In this study we have investigated the effect of surfactant, sodium dodecyl sulfate (SDS), on the dynamics of a single crude oil droplet, rising in a quiescent water column. Experiments were conducted in a tank, in which an oil droplet was released into a stagnant water column through a nozzle. The droplets ranging from 0.3 to 0.85 cm were produced from three different sized nozzles. The shape adopted by the emanating droplets varied from spherical to oblate. SDS concentrations were varied from 0 to 750 ppm in water. The adsorption of surfactant reduced the interfacial tension at oil‐water interface which resulted in generation of smaller sized droplets at the nozzle and caused the droplet to flatten. Consequently, the rise velocities of droplets decreased. A numerical model based on finite volume method was developed using commercial CFD package ANSYS Fluent®. The model employed volume of fluid method, suggested by Hirt and Nichols ( Journal of Computational Physics 1981 , 39 , 201), with an interface reconstruction technique based on piecewise linear representation for tracking the oil‐water interface. The influence of surface tension on the droplet dynamics was captured by including Continuum Surface force (CSF) approach suggested by Brackbill, Kothe, and Zemach ( Journal of Computational Physics 1992 , 100 , 335). The shape and rise velocities predicted from model were in good agreement with experimental data. The results from simulations were used, to analyze the wake structure and pressure distribution around the droplet. It was found that the smaller droplets which ascended in rectilinear path were associated with an axisymmetric wakes whereas larger and intermediate sized droplets in high SDS concentration wobbled as they ascended because of asymmetric wakes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.401
Threshold uncertainty score0.233

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.163
Teacher spread0.160 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2014
Admission routes1
Has abstractyes

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