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Record W2152413937 · doi:10.1002/chem.201303116

Small‐Peptide‐Based Organogel Kit: Towards the Development of Multicomponent Self‐Sorting Organogels

2013· article· en· W2152413937 on OpenAlexafffund
Rouzbeh Afrasiabi, Heinz‐Bernhard Kraatz

Bibliographic record

VenueChemistry - A European Journal · 2013
Typearticle
Languageen
FieldMaterials Science
TopicSupramolecular Self-Assembly in Materials
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Toronto
KeywordsSupramolecular chemistryNanotechnologySelf-assemblyMaterials scienceTemplateChromophoreSortingComputer scienceCombinatorial chemistryChemistryMoleculeOrganic chemistry

Abstract

fetched live from OpenAlex

The results presented here highlight the extremely useful nature of ultra-short peptides as building blocks in the development of smart multicomponent supramolecular devices. A facile bottom-up strategy for the synthesis of a small library of stimuli-responsive smart organogelators has been proposed based on the predictive self-assembly of ultra-short peptides. More importantly, the narcissistic self-sorting of the gelators has been evaluated as a simple method for the efficient co-assembly of a donor-acceptor dual-component gel, allowing the investigation of possible future applications of similar systems in the development of a supramolecular photo-conversion device. Interestingly, it was observed that the self-organization of the components can lead to highly ordered systems in which discrimination between compatible and non-compatible building blocks directs the effective organization of the chromophores and gives rise to the formation of an excited-state complex with exciplex-like emission. The current report may prove important in the development of organogel-based multicomponent smart devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.057
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.033
GPT teacher head0.228
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations43
Published2013
Admission routes2
Has abstractyes

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