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Record W2160863836 · doi:10.1039/c4sm00605d

Free energy of a long semiflexible polymer confined in a spherical cavity

2014· article· en· W2160863836 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueSoft Matter · 2014
Typearticle
Languageen
FieldChemistry
TopicElectrostatics and Colloid Interactions
Canadian institutionsUniversity of Waterloo
FundersNational Key Research and Development Program of ChinaFudan UniversityNational Natural Science Foundation of China
KeywordsPolymerChemical physicsSurface energyChain (unit)Materials scienceEnergy (signal processing)Surface (topology)ChemistryPhysicsComposite materialGeometryQuantum mechanics

Abstract

fetched live from OpenAlex

The free energy and conformational properties of a wormlike chain confined inside a spherical surface are investigated. We show that in the weak-confinement limit, the wormlike chain model exactly reproduces the confinement properties of a Gaussian chain; in such a case the confinement entropy dominates the free energy; in the strong-confinement limit, the free energy is dominated by the bending energy of the chain, which is forced to wrap around the confining surface. We also present a numerical solution within the crossover region between the two limits, solving the differential equation that the probability distribution function satisfies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.105
Threshold uncertainty score0.995

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0060.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.223
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it