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Record W2161033656 · doi:10.1098/rspa.2004.1323

Geodesic and re–coupling–induced limits to <i>S</i> <sub> 2 <i>n</i> </sub> group invariants of uniform ( <i>k</i> <sub>1</sub> ⋯ <i>k</i> <sub> 2 <i>n</i> </sub> ) dual tensorial sets in spin physics, or NMR: SR dynamical structure on {ℍ <sub> <i>v</i> </sub> } via polyhedral re–coupling and time–reversal invariance

2004· article· en· W2161033656 on OpenAlexaff
F.P. Temme

Bibliographic record

VenueProceedings of the Royal Society A Mathematical Physical and Engineering Sciences · 2004
Typearticle
Languageen
FieldChemistry
TopicMolecular spectroscopy and chirality
Canadian institutionsQueen's University
Fundersnot available
KeywordsCombinatoricsGroup (periodic table)MathematicsPhysicsRotation formalisms in three dimensionsBosonOrthogonal groupDiscrete mathematicsQuantum mechanicsGeometry

Abstract

fetched live from OpenAlex

For S n –based, uniform auxiliary dual tensorial (UDT) sets, explicitly with even maximal all–alike j i ( k i ) over v ≡ ( j 1 ⋯ j 2 n ), or ( k 1 ⋯ k 2 n ), sub–rank auxiliary labelling, the specific time–reversal invariance–dependent dual group invariants and their independent cardinalities (| SI | (2 n ) ) are fundamental to understanding simply reducible (SR) dynamical spin system structure over (Liouvillian) carrier space, a quantum physics property implicit in dual quasi–particle (QP) formalisms associated with, for example, uniform identical multiple spin NMR systems . Such UDT sets stand in total contrast to the distinct j i ( k i ) of ( j 1 ⋯ j″ n )(( k 1 ⋯ k″ n )) sub–rank orthogonal tensorial sets with their Z aa′ graph invariants which for reasons discussed in the text are of restricted validity. For UDTs as operator bases related to the (spin) interaction network–based tensors of high S n permutational NMR Hamiltonians (Liouvillians), the use of QP boson (superboson) formalisms and their dual projective maps (F. P. Temme 1993 Physica A 198 , 245–261) prove invaluable. Once the independent cardinality of the multiple invariants of these UDTs (alias the SU (2) × S 2 n group invariants) (here denoted | SI | (2 n ) ) are known in terms of democratic re–coupling (DR) and polyhedral combinatorial (PC) sampling applied to the time–reversal invariance (TRI) properties of the uniform multiple spin (sub–)system, so the SR dual carrier spaces , ℍ˜, ℍ˜ v follow directly as well–defined entities. For UDTs of general (2 n &gt; 6)–fold ensembles, the augmented models of TRI discussed here (i.e. beyond linear re–coupled Weyl forms) are essential, due to the presence of non–Abelian degeneracy. A regular geometric automorphic limit is established for sequential (2 n )–based | SI | (2 n ) total series, specific to (higher) uniform ( j 1 ⋯ j i ), ( k 1 ⋯ k i )–based dual tensors. By treating the | SI | (2 n ) obtained from the DR–based TRIs as group measures and invoking an automorphic geodesic augmentation, certain otherwise inaccessible, additional | SI | (2 n′ ) (and hence UDTs) may be established; these are based on sporadic higher (regular) (2 n ≫ 12)–fold ensemble invariants and are obtained via finite group duality properties implicit in the concept of group measures. The PC DR–based views of general (2 n ) interacting spins of UDTs expressed here give specific insight into dynamic structure over (explicit TRI invariant–defined) Liouvillian carrier spaces. This lattice point (Erdösian) view of DR shows that UDT invariants are distinct and more contracted than predicted by the earlier linear–re–coupling–based | D 0 ( U )|(⨷ SU (2)) approach. The presence of degeneracy in general high (2 n ) UDTs as non–Abelian entities ensures that the homomorphic–based, | D 0 ( U )| enumeration (with its implied linear graphical re–coupling) is invalid for high (2 n ) uniform (NMR) multi–spin systems whose TRI properties are governed by DR re–coupling. The prime focus of the report concerns the positive conceptual value of PC lattice–point–based DR, as applied to the S 2 n –invariants which define UDTs (of NMR) and their completeness. Brief contrasts with the earlier, more restricted O (2 k + 1) (overall) invariants of ( O ( n ) ⊃ ⋯ ⊃ G )–based democratic re–coupled quantum systems are given for completeness.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.103
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0010.001
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.217
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations3
Published2004
Admission routes1
Has abstractyes

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Same venueProceedings of the Royal Society A Mathematical Physical and Engineering SciencesSame topicMolecular spectroscopy and chiralityFrench-language works237,207