MétaCan
Menu
Back to cohort
Record W2161606490 · doi:10.1039/c1cc14113a

Click functionalized poly(p-phenylene ethynylene)s as highly selective and sensitive fluorescence turn-on chemosensors for Zn2+ and Cd2+ ions

2011· article· en· W2161606490 on OpenAlexaff
Yousef Pourghaz, Prateek Dongare, David W. Thompson, Yuming Zhao

Bibliographic record

VenueChemical Communications · 2011
Typearticle
Languageen
FieldChemistry
TopicMolecular Sensors and Ion Detection
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsFluorescenceTurn (biochemistry)ChemistryTriazoleSide chainIonYield (engineering)PhenylenePhotochemistryCombinatorial chemistryPolymer chemistryMaterials scienceOrganic chemistryPolymerBiochemistry

Abstract

fetched live from OpenAlex

Side-chain functionalized poly(p-phenylene ethynylene)s (PPEs) carrying triazole linkers, amino donors/receptors, and solubilizing groups have been found to yield remarkably high efficiency of fluorescence turn-on sensing for Zn(2+) and Cd(2+) ions in THF, and for H(+) and Cd(2+) ions in water.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.027
Threshold uncertainty score0.957

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.037
GPT teacher head0.265
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations40
Published2011
Admission routes1
Has abstractyes

Explore more

Same venueChemical CommunicationsSame topicMolecular Sensors and Ion DetectionFrench-language works237,207