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Record W2162143119

Unusual Isomerisation of Cubebene

2006· article· es· W2162143119 on OpenAlexaff
Christopher K. Jankowski, A. Savoie, Denis Lesage, J. R. Jocelyn Paré, Jacqueline M.R. Bélanger, Maria de Fatima Pereira, Valérie Thiéry, Thierry Besson, Olek Maciejak, Flavio Toma, Laurent Mauclairee, Xiangjun Liao

Bibliographic record

VenueRedalyc (Universidad Autónoma del Estado de México) · 2006
Typearticle
Languagees
FieldMedicine
TopicCancer Treatment and Pharmacology
Canadian institutionsEnvironment and Climate Change CanadaUniversité de Moncton
Fundersnot available
KeywordsChemistryIsomerizationMethanolExtraction (chemistry)ChromatographyMicrowave irradiationSolventMass spectrometryNuclear chemistryOrganic chemistry
DOInot available

Abstract

fetched live from OpenAlex

"Some sesquiterpenes extracted from Solidago canadensisL. in methanol underwent apparent isomerisation and the addition ofwater or methanol when the Soxhlet extraction was replaced by amicrowave heating method in polar solvents. The quantity of α-cubebene, one of these sesquiterpenes, during microwave extraction,was dramatically increased. In this study, we present the detailedcomparison of two cubebenes subjected to this isomerisation, 6-epi-α-cubebene and α-cubebene, as well as their solvent microwaveinduced addition products obtained under microwave irradiation inpolar solvents. The analysis is supported by high resolution bidimensionalNMR (1H, 13C), mass spectroscopy and selected isotopiclabelling experiments."

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.013

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.272
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2006
Admission routes1
Has abstractyes

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