Composite Noble‐Metal Films/H<sup>+</sup>‐Conducting Solid‐Polymer Electrolyte Assemblies: The Nitrate‐Reduction Activity in an Asymmetric Sandwich‐Type Reactor
Bibliographic record
Abstract
Abstract Asymmetric (Pt|Nafion|Pt–Pd–Cu) assemblies were fabricated to study the nitrate‐reduction reaction (NRR) at the cathode surface. The influence of the material composition, supplied current, and applied potential on the reactivity, kinetics, and product selectivity were thoroughly investigated. The cathode assembly consisting of 54 atom % Pt showed enhanced reactivity both in binary (Pt–Pd; k1≈10.7×10−3 min−1) and ternary (Cu–Pt–Pd; k1≈28.6×10−3 min−1) states. This composition was found to be highly nitrite‐selective (80 % in the binary state and 53 % in the ternary state). The mechanistic studies revealed that the reduction of nitrate ions to ammonia proceeded through a catalytic hydrogenation reaction followed by electrochemical hydrogen generation.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".